Aguirre Quintana María Jesús

Email: 
maria.aguirre@usach.cl
Teléfono: 
27 181 025

Abstract

Photo-electrocatalytic reactions formated by conducting polymers are studied. Conducting polymers are obtained from aza-macrocyclic transition complexes with oxidazable groups. We also study supramolecules assemblies from this kind of complexes.
Línea(s) de investigación: 
Sensores Electroquimicos y Fotoelectroquimicos.
Jerarquía: 
Titular
Grados académicos /educación: 
Doctor en Química, Universidad de Santiago de Chile (1992).
Química y Licenciada en Química, Universidad de Chile (1982)
Publicaciones: 
  • Aguirre, M. J., Muena, J. P., Gonzalez-Ulianoff, D., & Miranda, A. (2014). Fast electrochemical detection of non-desirable aging in bottled white wine. Journal of the Chilean Chemical Society, 59(2), 2526-2528. doi:10.4067/S0717-97072014000200029.
  • Arce, R., Aguirre, M. J., & Romero, J. (2014). Electrooxidation of free sulfite by an integrated system of glassy carbon modified electrodes with nickel phthalocyanines and membrane absorber in red wine. International Journal of Electrochemical Science, 9(12), 7916-7924. Retrieved from http://www.scopus.com/.
  • Arce, R., Aguirre, M. J., & Romero, J. (2014). Sensor for quantitative analytical determination of sulphite in wine using a system of modified electrode and amembrane absorption system. Paper presented at the ECS Transactions, 64(1) 37-42. doi:10.1149/06401.0037ecst.
  • Arce, R., Romero, J., & Aguirre, M. J. (2014). A glassy carbon electrode modified by a copolymer of co-tetrakis (para-aminophenyl)porphyrin and ortho-phenylenediamine. Characterization and electrocatalytic sulfite oxidation behavior of a basic extract from red wine. Journal of Applied Electrochemistry, 44(12), 1361-1369. doi:10.1007/s10800-014-0750-7.
  • Cotoras, M., Vivanco, H., Melo, R., Aguirre, M., Silva, E., & Mendoza, L. (2014). In vitro and in vivo evaluation of the antioxidant and prooxidant activity of phenolic compounds obtained from grape (vitis vinifera) pomace. Molecules, 19(12), 21154-21167. doi:10.3390/molecules191221154.
  • García, C., Fuenzalida, F., Ruiz, D., & Aguirre, M. J. (2014). Electrochemical, spectroscopic and morphological characterization of electrostatic self-assembled hybrids of tetracationic phosphonium porphyrins and CdTe quantum dots. Journal of Applied Electrochemistry, 44(12), 1345-1353. doi:10.1007/s10800-014-0741-8.
  • García, M., Aguirre, M. J., Canzi, G., Kubiak, C. P., Ohlbaum, M., & Isaacs, M. (2014). Electro and photoelectrochemical reduction of carbon dioxide on multimetallic porphyrins/polyoxotungstate modified electrodes. Electrochimica Acta, 115, 146-154. doi:10.1016/j.electacta.2013.10.142.
  • Marín, A. V., Aguirre, M. J., Muena, J. P., Dehaen, W., Maes, W., Ngo, T. H., Arévalo, M. C. (2014). Electro-reduction of oxygen to water mediated by stable glassy carbon electrodes modified by co(II)-porphyrins with voluminous meso-substituent. International Journal of Electrochemical Science, 10(5), 3949-3960. Retrieved from http://www.scopus.com/.
  • Velez, J. H., Aguirre, M. J., Cattin, L., Makha, M., & Bernede, J. C. (2014). Small molecules organic photovoltaic devices based on the planar heterojunction porphyrin derivates/fullerene. Journal of Porphyrins and Phthalocyanines, 18(5), 347-353. doi:10.1142/S1088424613501253.
  • Quezada, D., Honores, J., Aguirre, M. J., & Isaacs, M. (2014). Electrocatalytic reduction of carbon dioxide on conducting glass electrode modified with polymeric porphyrin films containing transition metals in ionic liquid medium. Journal of Coordination Chemistry, 67, 4090-4100. doi:10.1080/00958972.2014.974581.
  • Mendoza, L., Cotoras, M., Vivanco, M., Matsuhiro, B., Torres, S., & Aguirre, M. (2013). Evaluation of antifungal properties against the phytopathogenic fungus botrytis cinerea of anthocyanin rich-extracts obtained from grape pomaces. Journal of the Chilean Chemical Society, 58(2), 1725-1727. Retrieved from http://www.scopus.com/.
  • Arce, R., Márquez, P., Herrera, F., Aguirre, M. J., & Romero, J. (2013). Sulfite oxidation mediated by ortho-phenylenediamine / co(ii)- tetrakis(para-aminophenyl)porphyrin copolymers in acid medium. Journal of the Chilean Chemical Society, 58(4), 1982-1985. Retrieved from http://www.scopus.com/.
  • Díaz, C., García, C., Iturriaga-Vásquez, P., Aguirre, M. J., Muena, J. P., Contreras, R., . . . Isaacs, M. (2013). Experimental and theoretical study on the oxidation mechanism of dopamine in n-octyl pyridinium based ionic liquids-carbon paste modified electrodes. Electrochimica Acta, 111, 846-854. doi:10.1016/j.electacta.2013.08.103.
  • Isaacs, F., Dehaen, W., Maes, W., Ngo, T. H., Ruiz-León, D., Herrera, F., Aguirre, M. J. (2013). Direct 4-electron reduction of molecular oxygen to water mediated by cu-10-(4-aminophenyl)-5,15-dimesitylcorrole-modified electrodes. International Journal of Electrochemical Science, 8(3), 3406-3418. Retrieved from http://www.scopus.com/.
  • Muena, J. P., Villagrán, M., & Aguirre, M. J. (2013). Electrocatalytic oxidation and reduction of S(IV) species by 5,10,15,20-tetrakis-tetraferrocenylporphyrin-modified electrodes. International Journal of Electrochemical Science, 8(1), 621-633. Retrieved from http://www.scopus.com/.
  • Segura, R., Vélez, J., Godoy, F., Oyarzun, M. P., Sepúlveda, P., & Aguirre, M. J. (2013). Preparation of glassy carbon electrode modified with polymeric meso-tetrakistetrabromo thienylporphyrin for determination of cadmium and lead by anodic stripping voltammetry. International Journal of Electrochemical Science, 8(10), 12005-12014. Retrieved from http://www.scopus.com/.
  • Arce, R., del Río, R., Ruiz-León, D., Velez, J., Isaacs, M., del Valle, M. A., & Aguirre, M. J. (2012). Evidence for the formation of a copolymer by simultaneous electropolymerization of p-tetraaminophenyl porphyrin cobalt (II)) and o-phenylenediamine on glassy carbon. International Journal of Electrochemical Science, 7(11), 11596-11608. Retrieved from http://www.scopus.com/.
  • Dreyse, P., Quezada, D., Honores, J., Aguirre, M. J., Mendoza, L., Matsuhiro, B.. . Isaacs, M. (2012). Determination of S(IV) oxoanions at poly[ru(5-NO 2-phen) 2Cl] tetrapyridylporphyrin glassy carbon modified electrode. Electroanalysis, 24(8), 1709-1718. doi:10.1002/elan.201200038.
  • García, M., Carfumán, K., Díaz, C., Garrido, C., Osorio-Román, I., Aguirre, M. J., & Isaacs, M. (2012). Multimetallic porphyrins/polyoxotungstate modified electrodes by layer-by-layer method: Electrochemical, spectroscopic and morphological characterization. Electrochimica Acta, 80, 390-398. doi:10.1016/j.electacta.2012.07.039.Aguirre, M. J., Isaacs, M., Matsuhiro, B., Mendoza, L., Santos, L. S., & Torres, S. (2011). Anthocyanin composition in aged chilean cabernet sauvignon red wines. Food Chemistry, 129(2), 514-519. doi:10.1016/j.foodchem.2011.05.009.
  • Montes, C., Vélez, J. H., Ramírez, G., Isaacs, M., Arce, R., & Aguirre, M. J. (2012). Critical comparison between modified monier-williams and electrochemical methods to determine sulfite in aqueous solutions. The Scientific World Journal, 2012 doi:10.1100/2012/168148.
  • Vélez, J. H., Muena, J. P., Aguirre, M. J., Ramírez, G., & Herrera, F. (2012). Electrochemical oxidation of sulfite in aqueous solution by glassy carbon electrode modified with polymeric co(II) meso-tetrakis (2-thienyl)porphyrin. International Journal of Electrochemical Science, 7(4), 3167-3177. Retrieved from http://www.scopus.com/.
  • Lucero, M., Riquelme, M., Ramírez, G., Carmen Goya, M., Orive, A. G., Creus, A. H., Aguirre, M. J. (2012). A new modified electrode with a copolymer of aniline / fe(III)-tetrakis(para-aminophenyl)porphyrin: Test of its electrocatalytic activity toward the reduction of molecular oxygen and oxidation of ascorbic acid and sulfite ion. International Journal of Electrochemical Science, 7(1), 234-250. Retrieved from http://www.scopus.com/.
  • Calfumán, K., Dreyse, P., García, C., Aguirre, M. J., Beltrán, T., Guillamón, E., Isaacs, M. (2011). Characterization of PVC-tetraruthenated metalloporphyrins modified electrodes: Application as electrocatalyst in the nitrite reduction. Macromolecular Symposia, 304(1), 93-100. doi:10.1002/masy.201150613.
  • Calfumán, K., Aguirre, M. J., Cañete-Rosales, P., Bollo, S., Llusar, R., & Isaacs, M. (2011). Electrocatalytic reduction of nitrite on tetraruthenated metalloporphyrins/Nafion glassy carbon modified electrode. Electrochimica Acta, 56(24), 8484-8491. doi:10.1016/j.electacta.2011.07.057.
  • Caruso, F., Mendoza, L., Castro, P., Cotoras, M., Aguirre, M., Matsuhiro, B., Antonioletti, R. (2011). Antifungal activity of resveratrol against botrytis cinerea is improved using 2-furyl derivatives. PLoS ONE, 6(10) doi:10.1371/journal.pone.0025421.
  • Cotoras, M., Mendoza, L., Muñoz, A., Yáñez, K., Castro, P., & Aguirre, M. (2011). Fungitoxicity against botrytis cinerea of a flavonoid isolated from pseudognaphalium robustum. Molecules, 16(5), 3885-3895. doi:10.3390/molecules16053885.
  • Dreyse, P., Isaacs, M., Calfumán, K., Cáceres, C., Aliaga, A., Aguirre, M. J., & Villagra, D. (2011). Electrochemical reduction of nitrite at poly-[ru(5-NO2-phen) 2Cl] tetrapyridylporphyrin glassy carbon modified electrode. Electrochimica Acta, 56(14), 5230-5237. doi:10.1016/j.electacta.2011.03.028.
  • García, C., Domínguez, C., Aliaga, A., Matsuhiro, B., Mendoza, L., Aguirre, M. J., & Isaacs, M. (2011). Electrochemical properties of a conducting film derived from iron(II) tris(diaminopolypyridyl) complex in the S(IV) oxoanions reduction. Electroanalysis, 23(6), 1401-1409. doi:10.1002/elan.201000769.
  • Mendoza, L., Matsuhiro, B., Aguirre, M. J., Isaacs, M., Sotés, G., Cotoras, M., & Ricardo, M. (2011). Characterization of phenolic acids profile from chilean red wines by high-performance liquid chromatography. Journal of the Chilean Chemical Society, 56(2), 688-691. Retrieved from http://www.scopus.com/.
  • Torres, S., Ferraudi, G., Aguirre, M. J., Isaacs, M., Matsuhiro, B., Chandía, N. P., & Mendoza, L. (2011). On the ligand-to-metal charge-transfer photochemistry of the copper(II) complexes of quercetin and rutin. Helvetica Chimica Acta, 94(2), 293-300. doi:10.1002/hlca.201000227.
  • Aguirre, M. J., Chen, Y. Y., Isaacs, M., Matsuhiro, B., Mendoza, L., & Torres, S. (2010). Electrochemical behaviour and antioxidant capacity of anthocyanins from chilean red wine, grape and raspberry. Food Chemistry, 121(1), 44-48. doi:10.1016/j.foodchem.2009.11.088.
  • Calfumán, K., Aguirre, M. J., Villagra, D., Yañez, C., Arévalo, C., Matsuhiro, B., Isaacs, M. (2010). Nafion/tetraruthenated porphyrin glassy carbon-modified electrode: Characterization and voltammetric studies of sulfite oxidation in water-ethanol solutions. Journal of Solid State Electrochemistry, 14(6), 1065-1072. doi:10.1007/s10008-009-0916-0.
  • Calfumán, K., García, M., Aguirre, M. J., Matsuhiro, B., Mendoza, L., & Isaacs, M. (2010). Electrochemical reduction of S(IV) compounds in water-ethanol solutions at Nafion/tetraruthenated porphyrins glassy carbon modified electrodes. Electroanalysis, 22(3), 338-344. doi:10.1002/elan.200900298.
  • Cheuquepán, W., Villagra, D., Azócar, M. I., Ramírez, G., Chen, Y. Y., Matsuhiro, B., Aguirre, M. J. (2010). Effect of the number of substituents on the behavior of modified electrodes with cobalt porphyrins substituted with a different numbers of bis(methoxyphenyl) groups toward the oxidation of sulfite. Journal of the Chilean Chemical Society, 55(2), 253-256. Retrieved from http://www.scopus.com/.
  • Dreyse, P. A., Isaacs, M. A., Iturriaga, P. E., Villagra, D. A., Aguirre, M. J., Kubiak, C. P., Goeltz, J. C. (2010). Electrochemical preparation of conductive films of tetrapyridylporphyrins coordinated to four [ru(5-NO2-phen)2Cl]+ groups. Journal of Electroanalytical Chemistry, 648(2), 98-104. oi:10.1016/j.jelechem.2010.08.007.
Proyectos: 

DICYT

  1. Electrodos modificados. Nuevos materiales; 1999- 2000
  2. Electrodos modificados. Aplicación como sensonres.; 1994- 1998

FONDECYT

  1. 2010 - 2014; "Determinación de parámetros electroquímicos para determinación de envejecimiento en vinos", Investigador personal.
  2. 2006- 2008; "Proyecto  Anillo, Programa Bicentenario en Ciancia y Tecnología, Conicyt/Banco Mundial, “Diseño de un sensor electroquímico para sulfitos y determinacion de la capacidad antioxidante de fenoles en vinos" Director.
  3. 2005- 2005; "Nuevos materiales conductores: copolimeros anilina­-porfirina y polimeros de porfirina con apilamiento supramolecular". Fondecyt 1050306 responsable
  4. 2001- 2004; "Foto-Electro Activación de Polimeros de Coordinación Para Ser Usados Como Catalizadores y Sensores de Contaminantes de Aire". Fondecyt 1010695, responsable
  5. 1998- 2000; "Síntesis, caracterización propiedades electrocatáliticas de polímeros conductores de Tetraminoftalocinaninas de Co y de Fe"

FONIS

  1. 2010 - 2014; "Electro and photoelectro-catalytic synthesis of urea and urethanes from carbon dioxide and nitrite or amines, on tetraruthenated pophyrins-modified electrodes in water and ionic liquids: an aproach to the green electrochemistry concept", Coinvestigador.

FONDAP

  1. 2015 - 2017; "Centro de Investigación en Líquidos Iónicos CILIS", Coinvestigador
  2. 2012 - 2014; "Centro de Investigación en Líquidos Iónicos CILIS", Coinvestigador
Otras actividades relevantes: 

Laboratorio de Polimeros Conductores Bipotenciostato pine 1 Bipotenciostato Pine 1 Bipotenciostato Voltalab 1 rotador de electrodo Radiometer 1 Espectrofotómetro Analytikjena 1 Potenciostato frabricado en la Universidad 1 Equipo de Impedancia electroquímica Voltalab. 1 generador de ondas cuadradas Voltalab. Lámparas, filtros, celdas y electrodos para espectroelectroquímica. Sistema de Síntesis de Compuestos de Coordinación. 1 Potenciostato CHI. 1 Bipotenciostato CHI