Costamagna Martra Juan Alberto

Email: 
juan.costamagna@usach.cl
Teléfono: 
27 181 045
Sitio web: 
http://www.experts.scival.com/UdeSantiago/expert.asp?n=JUAN%20A%20COSTAMAGNA%20M…
Abstract
Synthesis and characterization of coordination compounds with cyclic and acyclic ligands and application of these compounds to catalytic activation of small molecules.
Línea(s) de investigación: 
Química de compuestos de coordinación
Jerarquía: 
Titular
Grados académicos /educación: 
Doctor en Química, Universidad de Buenos Aires, 1970.
Licencia en Ciencias Químicas, Universidad de Chile (Revalidación), 1969
Publicaciones: 
  1. J.Costamagna, L.E.Lillo, B.Matsuhiro(*), M.Noseda, M.Villagrán, “Ni (II) Complexes with Schiff Bases Derived from Amino Sugars”, Carbohydr. Res., 2003,338,1535-1542. IF: 2.332.
  2. A.Ríos, G.Estiú, J.Costamagna(*), G.Cárdenas-Jirón, “Theoretical and Experimental Study of the Electronic Structure and Spectra of Ni (II) Tetraazadinaphto[14] Annulenes  Complexes”, J.Coord.Chem., 2003,54,1257-1267. IF: 1.547.
  3. M.Isaacs, J.C.Canales, A.Riquelme, M.Lucero, M.J.Aguirre, J.Costamagna(*) “Contribution of the Ligand on the Electroreduction of CO2 Catalized by a Cobalt (II) Macrocyclic Complex”,  J.Coord.Chem., 2003,54,1193-1201. IF: 1547.
  4. F.Caruso(*), L.Massa, A.Gindulyte, C.Pettinari, F.Marchetti, R.Pettinari, M.Ricciutelli, J.Costamagna, J.C.Canales, J.Tanski, M.Rossi,   “(4-Acyl-5-pyrazolonato)titanium Derivatives:  Polymerization, Hydrolysis, Voltammetry and DFT study”,  Eur.J.Chem., 2003, 3221-3232. IF: 5.925.
  5. A.Ríos., M.Villagrán, J.Costamagna(*), G.Ferraudi, “Intermediates in the Ni II (Naphto2[14] -2,4,6,9,11,13 –hexaene N4)–catalyzed Photoreduction of CO2 to CO.  A Pulse-Radiolytic and Flash- Photochemical Study”, J.Coord.Chem., 2003,54,1233-1244. IF: 1.547.
  6. D.Venegas(*) , M.Campos, A.B.P.Lever), J.Costamagna, R.Latorre, W.Hernández,  “A Family of Ruthenium Complexes Containing the Non-innocent Ligand o-benzoquinonediimine. An Infrared Structural Interpretation”, J.Chil.Chem.Soc., 2003,48,75-79. IF: 0.532
  7. G.Cornejo, G.Ramírez, M.Villagrán, J.Costamagna, E.Trollund, M.J.Aguirre(*), “Electro-polymerization and Electrocatalytic Behavior of Electrodes Modified with Fe and Non-metalled Tetraaminophenylporphyrins: Effect of the Position of the Amino Group on the Ligand”,  J.Chil.Chem.Soc., 2003,48,49-55. IF: 0.532.
  8. G.Estiu, J.Canales, J.Ramírez, J.Costamagna(*), “Influence of the Solvent in the Electronic Spectra of Azabipyridine Macrocycles of Zinc(II) and Nickel(II), J.Coord.Chem., 2003,54,193-214. IF: 1.547.
  9. J.Costamagna(*), F.Caruso, M.Rossi, M.Campos, J.Canales, J.Ramirez, “Precursors of Hexa-azamacrocycles. Synthesis and X-Ray Structure of 2,9-Diaminophenanthroline-bisacetate-Co(II) and 6,6’-Diaminobipyridine-bisacetate-M(II) (M=Ni,Cu)”, J.Coord.Chem., 2003,54, 247-260. IF: 1.547.
  10. G.Ramirez, M.Lucero, A.Riquelme, M.Villagrán, J.Costamagna, E.Trollund, M.J.Aguirre(*), “A supramolecular cobalt-porphyrin-modified electrode toward the electroreduction of CO2”, J.Coord.Chem., 2004, 57, 249-255. IF: 1.547.
  11. A.Ríos, J.Costamagna, G.Cárdenas-Jirón(*),  “Fukui Indexes Applied to the Reduced and Non reduced Species of the Ni(II)  Tetraazadinaphto [14] Annulene Complex and its Protonated Derivative”,  J.Phys.Chem. A, 2004,108,7253-7260. IF: 4.805. 
  12. A.Ríos, M.Isaacs, M.Villagrán, J.Zagal, J.Costamagna(*), “Electrochemical Reduction of Carbon Dioxide in Presence of [NiII-5,7,12,14-tetramethyl-dinaphtho[b,i][1,4,8,11] tetra-aza [14]annulene]++ Cation”, J.Arg..Chem.Soc, 2004,92,63-71. IF: 0.109.
  13. P.Cáceres, J.Costamagna, A.Danil de Namor, B.Matsuhiro(*), ”Lower Rim p-tert-butylcalix[4]arene Derivatives Containing Galactitol Pendants. Complexation of 5,11,17,23-tetrakis-(1,1-dimethyl)-25,27-dihydroxy-26,28-Bis-2-N-(1-deoxy-D-galactityl)aminoethoxy calyx[4]arene with Pb(II) and F(-I), J.Chil.Chem.Soc., 2004,49,281-284. IF: 0.532.
  14. G.Ferraudi, J.C.Canales, B.Kharissov, J.Costamagna(*), J.Zagal, G-Cárdenas-Jirón, M.Paez,  “Synthetic N.Substituted Metal Aza-Macrocyclic Complexes: Properties and Applications”, J.Coord.Chem.,2005,58, 89-109. IF: 1.547.
  15. M.Isaacs, F.Armijo, G.Ramirez, E.Trollund, S.R.Biaggio, J.Costamagna, M.J.Aguirre(*), “Electrochermical Reduction of CO2 mediated by PolyM-Amino phthalocyanines (M=Co,Ni,Fe): poly-Co-tetraminophthalocyanine, a selective catalyst”, J.Mol.Cat.A:Chem, 2005,229,249-257. IF: 2.947
  16. M.Gulppi, M.Paez, J.Costamagna, G.Cardenas-Jiron, F.Bedioui, J.Zagal(*), “Inverted Correlations between Rate Constants and Redox Potential of the catalyst for the Electrooxidation of 2-aminoethanediol Mediated by Surface Confined Substituted Cobalt-phthalocyanines”, J.Electroanal.Chem., 2005, 580,50. IF: 2.905.
  17. V.Paredes, G.Cardenas-Jirón(*), D.Venegas, J.Zagal, M.Paez, J.Costamagna,  “Through Space and Through Bond Mixed Charge Transfer Mechanisms on the Hydrazine Oxidation by Cobalt(II) Phthalocynanine in the Gas Phase”, J.Phys.Chem. A, 2005,109,1196-1204. IF:4.805.
  18. J.Henríquez, L.Padilla, M.Páez , J.Zagal, J.Costamagna, G.Cárdenas-Jirón(*), M.A.Rubio, “The Influence of Aniline and its Derivatives on the Corrosion Behaviour of Copper in Acid Solution: A Theoretical Approach”, Theochem, 2005, 757,1-7. IF: 1.437.
  19. C.Barrera, I. Zhukov, E.Villagra, F.Bedioui, M.Páez, J.Costamagna, J.Zagal(*), “Trends in reactivity of unsubstituted and substituted cobalt-phthalocyanines for the electrocatalysis of glucose oxidation”, J.Electroanal.Chem.,2006,589, 212-218. IF: 2.905.
  20. M.Villagrán, J.Costamagna(*), J.Zagal, G.Cárdenas-Jirón,  M.Páez, “Nickel(II) complexes with tetraaza macrocycles in the electrocatalytic oxidation of sulfite”, J.Coord.Chem., 2006,59,  1467-1475. IF: 1.547.
  21. G.Cárdenas-Jirón(*), V.Paredes-García, D.Venegas, J.Zagal, M.Páez, J.Costamagna, “Theoretical Modeling of the Oxidation of Hydrazine by Iron(II) Phthalocyanine in the Gas Phase. Influence of the Metal Carácter”, J. Phys. Chem. A, 2006,110, 11870-11875. IF: 4.805.
  22. A.Rios, M.Villagrán, F.Caruso, J.P.Muena, E.Spodine, D.Venegas, L.Massa, L.J.Todaro, J.Zagal, G.Cárdenas-Jirón, M.Páez, J.Costamagna(*), “Electrocatalytic Reduction of Carbon Dioxide Induced by Bis-(N-R-2-Hydroxy-1-Naphthaldiminato)-copper(II), (R=n-Octyl, n-Dodecy).  Magnetic and Theoretical Studies and the X-Ray structure of bis-(N–n-Octyl-2-Hydroxy-1-naphthal diminato)-copper(II)”, Inorg.Chim.Acta, 2006,359,3947-3953. IF:1.846.
  23. A.Arancibia, J.Henríquez, M.Paez, L.Padilla, J.Zagal(*), J.Costamagna, G.Cardenas-Jirón, “Influence of 5-chloro and 5-methyl Benzotriazole on the Corrosion Of Copper in Acid Solution: an Experimental and a Theoreticl Approach, J.Solid State Electreochem., 2006,10,  894-904. IF: 2.131.
  24. F.Armijo, G.Ferraudi, F.Isaacs, M.J.Aguirre, J.Costamagna(*),  “On the photo- and electro-induced polymerization of M(tetrakis(x-aminophenyl) porphyrin), where x = 2,3 or 4 and M = Zn(II) or Ni(II)”, Inorg.Chim.Acta, 2006,359,2281-2284. IF: 1.846.
  25. J.A.Clausen, G.Ochoa, M.Paez, J.Costamagna, M.Gulppi, T.Nyokong, F.Bedioui, J.H.Zagal(*),  “Volcano Correlations for the Reactivity of Surface-confined Cobalt N4-macrocycles   for the Electrocatalytic Oxidation of 2-mercaptoacetate”, J.Solid State Electrochem., DOI 10.1007/s10008-007-0336-y, Springer, 2007. IF: 2.131. 
  26. J.P.Muena, M.Villagrán, J.Costamagna(*), M.J.Aguirre, “Dinaphtho tetraza[14]annulene Copper(II) Complexes in the Electrocatalytic Reduction of Carbon Dioxide and Bisulfite anion”, J.Coord.Chem., 2008,61,479-489. IF: 1.547.
  27. E.Villagra, F.Bedioui, T.Nyokong, J.C.Canales, M.Sancy, M.Paez, J.Costamagna, J.H.Zagal(*), “Tuning the redox properties of Co-N4 macrocyclic complexes for the catalytic electrooxidation of glucose”, Electrochimica Acta, 2008,53,4883-4888. IF: 3.832.
  28. L.M.Blanco, L.T.Conzalez, B.I.Kharissov(*), E.N.Aguilera, A.D.Garnovskii, F.E.Longoira, J.Costamagna, G.S.Borodkin, M.S.Korobov, “Direct electrochemical synthesis of a nickel complex with 5,10,15,20-tetrakis(p-hydroxyphenyl) porphyrin”, Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2008,38,503-513. IF: 0.504.
  29. M.Villagrán, J.P.Muena, J.Costamagna, J.Zagal, A.G.Lappin, G.Ferraudi(*), “Oligomerization of the Cu(II) and Ni(II) tetraazaanulene complexes: a pulse radiolysis study of the associated reaction mechanism”, Inorganica Chimica Acta, 2008,362,2177-2182. IF: 1.846.
  30. M.Villagrán, J.P.Muena, G.Ferraudi, J.H.Zagal, J,Costamagna(*), “Electrochemical Reduction of S(IV) species in aqueous medium by glassy carbon electrodes modified with polymeric copper(II) tetra-aza-annulene complexes”, Journal of Coordination Chemistry, 2009,62,141-149. IF: 1.547.
  31. N.P.Chandia, J.C.Canales, I.Azocar, S.Vanlaer, V.G.Pawar, W.M.De Borggraeve(*), J.Costamagna, W.Dehaen,  “Synthesis of 5,5’-dialkyl-6,6’-dichloro-2,2’-bipyridines”, Synthetic Communications, 2009,331-13. IF: 1.062.
  32. M.Villagrán, J.P.Muena, J.Costamagna, J.Zagal, A.G.Lappin, G.Ferraudi(*), G.Estiú, "The Cu(II) tetraazannulene-catalyzed reduction of S(IV) species. A pulse radiolysis and theoretical study of the associated reaction mechanism”, Helvetica Chimica Acta, 2009,92,339-356. IF: 1.478.
  33. M.Villagrán, F.Caruso, M.Rossi, J.H.Zagal, J.Costamagna(*), “Substituent  Effects on Structural, Electronic and Redox Properties of Bis(N-alkyl-2-hydroxy-1-naphthaldiminato)copper(II) Complexes Revisited. Inequivalence in Solid and Solution State Structures by Electronic Spectra and X-Ray Diffraction are Explained by DFT Data”,  Eur.J.Inorg.Chem., 2010,1373-1380. IF: 3.049.
  34. L.Lemus, J.Guerrero, J.Costamagna, G.Estiú, G.Ferraudi(*), A.G.Lappin, A.Oliver, B.C.Noll, “Unfolding of the Helicate [Cu2(1,3-bis(9methyl-1,10-phenanthrolin-2-yl)propane]2+. Coupling of the Chlorocarbon Dehalogenation to the unfolding Process”, Inorg.Chem., 2010,49,4023-4035. IF: 4.601.
  35. J.Guerrero(*), L.Cortez, L.Lemus, L.Farías, J.Costamagna, C.Pettinari, M.Rossi, F.Caruso, “Spectroscopic and Electrochemical Properties of Heteroleptic Cationic Copper Complexes bis(diphenylphosphino)alkane-(2,2’-biquinoline)copper(I). Crystal Structure of bis(diphenylphosphino)ethane-(2,2’-biquinoline)copper(I) Perchlorate”, Inorg.Chim. Acta, 2010, 363,3809-3816. IF: 1.846.
  36. L.Lemus(*), J.Guerrero, J.Costamagna, D.Jara, J.Zagal, A.Olivier, G.Ferraudi, G.Lappin, “Synthesis and Structural Study of a Circular Trimetallic Cu(I) Helicate”, Acta Cryst., 2011, A67, C753. IF: 2.076.
  37. P.Hermosilla, P.E.Car, A.Vega, J.Costamagna, F.Caruso, J-I.Pivan, E.Le Fur, E.Spodine, D.Venegas(*), “New Structures Based on the Mixed  Valence Poly oxometalate Cluster [V12B18O60H6]n-“, CrystEngComm, DOI: 10.1039/c2ce25436k, 2012. IF:  3.842.
  38. M.Villagrán, F.Caruso, M.Rossi, J.Zagal, J.Costamagna(*), “Structure, Electronic, and CV Properties of Hydroxy-naphthaldehyde Schiff Base Copper(II) Complexes Derived from Alkyl Amines: X-ray Structure of Bis-(n-i-propyl-3-hydroxy-2-naphthaldiminato)copper(II)”, J.Coord.Chem, 2012,65,3752-3765. IF: 1.547.
Proyectos: 

Investigador responsable

  1. FONDECYT “Procesos de Transferencia de Carga en Electrocatálisis y Corrosión Electroquímica”, Proyecto Líneas Complementarias, 2002-2006, FONDECYT, Conicyt, Chile.
  2. Proyecto de Cooperación Científica y Técnica Chile-Comunidad Flamenca de Bélgica. “Synthesis and Properties of Hexaazamacrocycles Derived from Hetero-Diels-Alder Cycloaddition Reactions of Oxazinones and Pyrazinones”, 2004-2005.
  3.  DICYT 2007-2009.

 

Co-Investigador

  1. FONDECYT, “Indices de Reactividad de Complejos Metálicos Confinados en Superficies Electródicas en Reacciones de Transferencia de Carga, FONDECYT, Conicyt, Chile,          2006-2009.
  2. FONDECYT, “Hybrid Molecular Electrode Materials Containing Metallomacrocyclics, Carbon Nanotubes and Self Assembled Monolayers for Electrocatalysis and Electroanalysis”, FONDECYT, Conicyt, Chile, 2010-2013.  
Otras actividades relevantes: 

Número de tesis dirigidas en los últimos 10 años:

Magister:       Dirigidas:        1                En desarrollo:             0

Doctorado:    Dirigidas:        4                En desarrollo:             1

 

otras publicaciones y patentes

  1. J.Costamagna, B.Kharisov, Editores Invitados,  “Ligandos Azamacrocíclicos y sus Complejos Metálicos”, J.Coord.Chem.,2003, 54, 183-492. IF: 0,532.
  2. J.Costamagna, M.Issacs, M.J.Aguirre, G.Ramírez, I.Azócar, “Electroreduction of CO2 Catalized by Metallomacrocycles”, Capítulo 5, pags 191-254 en “N4—Macrocyclic Metal Complexes”, F.Bedioui, J.P.Dodelet, J.Zagal, Editores, Spinger, 2006.
  3. J.C.Canales, J.Costamagna(*),  “Synthetic Azamacrocyles in the Reduction of Carbon Dioxide: Review and Perspectives”, Anales de la Academia de Ciencias Exactas Fisicas y Naturales, 2006,58,21-27.
  4. J.Costamagna(*), Co-Editor, “Número Especial Dedicado a Alfredo Mederos”, J.Coord. Chem., 2009,62,1-149. IF: 1.547.
  5. D.Venegas, P.Hermosilla, J.Costamagna, E.Spodine, A.Vega, V.Paredes, E.Le Fur, “A Novel Coordination Polymer Based on Decavanadates Units Linked by Copper(II) Ethylenediamina Complexes”, Macromol Symp, 2011,304,80-86. IF:
  6. J.Costamagna, F.M.Rabagliati, B.L.Rivas, Symposium Editor, “Macromolecular Simposia”, 2011,304, 1-125.

 

Otras actividades relevantes

Comité editorial revistas científicas

  • JOURNAL OF COORDINATION CHEMISTRY
  • COMMUNICATIOS IN INORGANIC SYNTHESIS

 

Referee de revistas internacionales

  • Inorganic Chemistry,
  • Inorganica Chimica Acta,
  • Journal of Molecular Structure

 

Revisor de proyectos

  • Banco Iberoamericano de Evaluadores de Proyectos de Investigación,
  • Proyectos CONICET, Argentina.
  • Proyectos  PEDECIBA, Uruguay.

 

 Participación en claustro de doctorados

  • Doctorado en Química, USACH.